Two point bent beam, nace tensile, cring and dcb stress. Sulfide stress cracking of nickelcontaining lowalloy steels. We studied the stress corrosion cracking and revealed some interesting results as follows. Sulfide stress cracking ssc vs hydrogen induced cracking hlc. In this chapter the terms eac and scc are generally interchangeable. Localised corrosion is often associated wuth chloride ions in aqueous environments. Ferritic stainless steels, on the other hand, tend to be fairly resistant to hydrogen stress cracking due. The lower molecular weightcompounds, however, such as those encountered in petroleum production and used to odorize natural gas, should be expected to cause sulfiderelated attack sulfide stress cracking or hydrogenaffected cracking in susceptible steels in the presence of water. Grades with high resistance to chlorideinduced stress corrosion cracking scc duplex stainless steels, austenitic stainless steels with a high nickel content 25%. Occurrences of cracking in lowalloy nickel steels, e. Sulfides present in aqueous solution are responsible for stress corrosion cracking scc of steel, and is also known as sulfide stress cracking.
It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Standard material requirements sulfide stress cracking. In the presence of water and hydrogen sulfide, atomic hydrogen is produced and enters the steel, recombining at discontinuities to. Stress corrosion cracking of nickel based alloys in watercooled nuclear reactors.
Alloys 825, 925, 625 and 725 all contain 42% or greater nickel and as a result are all very resistant to stress corrosion cracking in water containing chlorides. The purpose of this booklet, therefore, is to help materials engineers identify those applications and to provide data to support the use of stainless steels in the hightemperature, corrosive environments that may be encountered. Hydrogen stress cracking can affect several different types of metals such as high strength structural, carbon, and low alloy steels, along with titanium, nickel, and aluminium alloys. The nace mr0175 standard for sulfide sulphide stress corrosion cracking resistant metallic materials for oilfield equipment is now also available as an iso standard 15156. Sulfide stress cracking, a form of hydrogen embrittlement, first became a serious problem in the oil industry in 1951. Factors governing stress corrosion cracking scc of low strength, low alloy nickel steels e. Sulfide stress corrosion cracking in lowalloy steel inertia friction. Martensitic stainless steels, sulfide stress cracking, xps. Cring specimens of 20%, 33% and 50% cold worked ni200 were free from.
The postweld the postweld heat treatment pwht is used to reduce the cracking susceptibility of the f22. Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range. Cracking resistant carbon and low alloy steels, and. For this reason, along with toxicity risks of hydrogen sulfide gas, it is essential that water muds be kept entirely free of soluble sulfides and especially hydrogen sulfide at low ph. The susceptibility of a high strength low alloy nanostructured steel to sulfide stress corrosion cracking sscc resistance is assessed. Pdf effect of postweld heat treatment on the sulfide. February 19, 2017 by mariano iannuzzi in a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. Cracking of alloy 800h reformer riser quest integrity group. Hydrogen embrittlement characteristics, especially pertinent to sulfide stress cracking, or steels has been investigated to a great extent. Novel schiff base amino acid as corrosion inhibitors for carbon steel in cosaturated 3. Hydrogen embrittlement characteristics, especially pertinent to sulfide stress cracking, of steels has been investigated to a great extent. In this environment, not only is hydrogen sulfide stress cracking a concern, but the presence of.
Stress corrosion cracking test results for c ring test pieces in a simulated sour well environment containing free sulphur are shown in table 9 of the attached document. Tib and mncrmo was evaluated using constant load tensile test and slow strain rate test in nacetm0177 environment. Results of this investigation on the sulfide stress cracking ssc of cast and wrought commercial astm lowalloy steels containing ni showed that the apparent nickel effect is probably an artifact of the divergence of the proportional limit of a steel from its 0. Pdf stress corrosion cracking scc of nickelbased alloys. Fabricating nickel alloys to avoid stress relaxation cracking. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Austenitic stainless steels are susceptible to caustic stress corrosion cracking scc above 121c. Chloride stress corrosion cracking in austenitic stainless. Dec 19, 2019 ssc is a form of spontaneous brittle breakdown in occurring in highstrength alloys and steels when it comes in contact with humid hydrogen sulfide as well as sulfidic atmospheres. Sulfide stress cracking of stainless steel 410 in sour crude. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress. Stress corrosion cracking of nickel based alloys in water. Some troubles by hydrogen sulfide stress crrosion cracking of austenitic stainless steels have occurred in japanese refineries.
Hydrogen induced cracking hic is a form of tiny blistering damage caused by a high concentration of hydrogen in steel. Testing of superduplex stainless steel for sour service. This article summarises the requirements for all types of stainless steel austenitic, ferritic, duplex, martensitic and precipitation hardening stainless steels which. H 2 s can cause sulfide stress cracking of stainless steels. Susceptibility of steels containing cr, ni, and mo in h s. These alloys offer supreme resistance to cracking in sour and chloride containing conditions. The cost of the common stainless steels is substantially determined by the cost of ingredients. Investigations of hydrogen embrittlement and sulfide stress cracking of nickel and nickel base alloys have not been quite as extensive as in the case of steels. When sulfides are present in caustic solutions the scc has been reported to occur at lower temperatures. Standard material requirements materials resistant to. Surface flaws also influence the hydrogen cracking or sulfide stress cracking of moderate to highstrength steels exposed to brine containing h2s.
Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Sulfide stress cracking is most severe at ambient temperature, particularly in the range of 20 to 120f 6 to 49c. Sulfide stress cracking nace mr01752002, mr0175iso. The possibility that cold work affects the resistance to sulphide stress cracking is not.
First, the potential commercial impact of highstrength and hightoughness nickel alloy steels is. The environment causing stresscorrosion cracking scc at the top of a distillation tower in a crude oil refinery was reproduced in the laboratory. Environmental embrittlement of nickel and nickelbase alloys. Super duplex steels with pren above 40 should be used up to 450of or 232oc for h2s partial pressure about 3 psia. Making the grade nickel and nickel alloy seamless pipe. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Sulfide stress cracking of nickel containing lowalloy steels. Sulfide stress cracking is prevented by minimizing the hardness and strength of the.
Sulfide stress cracking of nickelcontaining lowalloy steels microbially influenced corrosion of steels by oxidative degradation and corrosiveness of biodiesel. Stress corrosion cracking 2205 is a cost effective solution for many applications where 300 series stainless steels are susceptible to chloride stress corrosion cracking scc. Hydrogen sulfide stress corrosion cracking in materials. Sulfide stress cracking of nickel steels corrosion. Effect of nickel on hydrogen permeation in ferriticpearlitic low alloy steels publication. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Figure 1 illustrates typical microstructural features common to stress relaxation cracks found in alloy 800h. This article is reporting the sulfide stress cracking of stainless steel 410 in annealed condition. Since strength of steel parallels its hardness, the empirically determined maximum hardness specified in rc22. Sulfide stress corrosion study of a super martensitic stainless steel. A systematic evaluation of the sulfide stress cracking ssc behavior of five steels with nickel contents ranging from 0 to 3 pct was conducted in an acidified chloride solution saturated with h 2 s at room temperature nace solution. Hydrogen sulfide stress corrosion cracking of stainless steels.
Subsequent improvements in the metallurgy of steels for highpressure gas and oil wells and improved selection methods for highstrength alloys have been based on laboratory test methods. The most common forms of wet h 2 s cracking are hydrogen induced cracking hic, stress oriented hydrogen induced cracking sohic, and sulfide stress cracking ssc. The effects of sulfide stress cracking on the mechanical properties. Hydrogen sulfide hsub 2s has long been associated with the cause of corrosion damage and sulfide stress cracking ssc in high strength steels and high hardness weldments used in oil and gas production, petroleum refining, and petrochemicalchemical processing. The coriou effect presents the latest information on brittle failure of metals in corrosive chemical environments under the influence of tensile stresses. Corrosion resistance relies on a good supply of oxygen. Sulfide stress cracking susceptibility of nickel containing. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Nickel sulfide is an inorganic compound with the formula nis.
Hydrogen sulfide is known to cause or assist in the mechanism of cracking with many alloy types including low carbon steels, low alloy steels, alloy steels, tool steels. The effects of mercaptans on various metals aong website. Sulfide stress cracking of nickelcontaining lowalloy steels about. The cost of nickel and its addition to stainless steel. Nickel based alloys 7 duplex stainless steels 304, 316, 317, 321, 347 3. It is a form of hydrogenrelated cracking and can have two distinct morphologies. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. The effect of nickel content on the environmental assisted cracking. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stress corrosion cracking.
Which alloy is for sulfide stress and stress corrosion cracking. Nickel can have a beneficial effect on sulphide stress cracking ssc resistance in duplex stainless steels. Sulfide stress corrosion cracking, also known as sulfide stress cracking ssc, is a stress corrosion cracking phenomena that occurs in the presence of hydrogen sulfide. Wet h 2 s cracking can occur in susceptible steels exposed to aqueous environments containing hydrogen sulfide. This paper discusses a study of the role of sulfide in caustic solutions on scc of austenitic stainless at t50c. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Effect of postweld heat treatment on the sulfide stress cracking of. Hydrogen sulphide stress corrosion cracking in materials for. Stainless steels can be susceptible to certain localised corrosion mechanisms, namely crevice corrosion, pitting, intercrystalline corrosion, stress corrosion cracking and bimetallic galvanic corrosion. Van wortels paper 1 refers specifically to the cracking of austenitic alloys such as 321 and 347 stainless steels, nickel based alloys such as 617 and of most relevance in the present case, alloy 800h. Abstract results of this investigation on the sulfide stress cracking ssc of cast and wrought commercial astm lowalloy steels containing ni showed that the apparent nickel effect is probably. The applications for stainless steels in petroleum refining are many and varied.
The role of nickel in the sulfide stress cracking ssc resistance of lowalloy steels has been in dispute for many years. Sulfide stress cracking ssc also known as sour gas cracking sour gas. Stress corrosion cracking of low strength, low alloy. Ssc is a form of spontaneous brittle breakdown in occurring in highstrength alloys and steels when it comes in contact with humid hydrogen sulfide as well as sulfidic atmospheres. Stress corrosion cracking of stainless steels in hydrogen. It was an acidified hydrogen sulfide solution with a ph value up to 3. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Previous studies of ssc of stainless steel 410 have focused on improper tempering of this alloy. Effect of coldwork on sulphide stress cracking resistance twi. Corrigendum sulfide stress cracking of nickelcontaining. Stress corrosion cracking behavior of nickel base alloys. Sour service limits of dualcertified 316316l steel twi.
Highperformance age hardenable nickel alloys solve. Superduplex stainless steels are widely used by the oil and gas industry for their combination of corrosion resistance, chloride stress corrosion cracking resistance, high strength and weldability. Materials selection properties the levels of strength in age hardened materials becoming increasingly important, particularly for offshore applications that are exploiting highpressure deep well. A cring type test, widely employed in the petroleum industry, has been adopted. Comparing stainless steel and other metals machine design. Hydrogen sulfide stress corrosion cracking in materials for.
From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickel copper alloys, nickel molybdenum alloys, nicrmo alloys and nicrfemo alloys. Material considerations for sour gas systems webex presentation february 10, 2016. The cracking is affected by stress including stress concentration and residual stress. All of the steels were lowalloy, structural, or pressure vessel steels that are heat treatable to high strength levels with high toughness. Stress corrosion cracking of ferritic steel weld metal the effect of nickel.
Dashed lines indicate the typical smys range for nickel alloy steels compliant with iso 151562 requirements, with permission of. Results of this investigation on the sulfide stress cracking ssc of cast and wrought commercial astm lowalloy steels containing ni showed that the apparent nickel effect is probably an. Stress corrosion cracking facts and how to reduce the. Which alloy is for sulfide stress and stress corrosion. T g gooch reports a study of the effect of nickel on the stress corrosion cracking behaviour of weld metals appropriate to structural and pipeline steels. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible. Provide a consistent and reliable method to predict the threshold stress which initiates cracking kisscc. Material selection for sour service environment pipeline. Among the most prone to sulfide stress cracking include valve trim, blowout preventer hard parts and tool joints. Which alloy is best to resist sulfide stress cracking and stress corrosion cracking. Evaluate the susceptibility to sulfide stress corrosion cracking of both high strength low alloy carbon steels in sour service conditions as well as low yield point high ductile steels.
Nickel and sulphide stress cracking in duplex steels twi. This is a complex topic, other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Many nickel sulfides are known, including the mineral millerite, which also has the formula nis. Ni 1%mo, which exhibits good corrosion and mechanical properties in sour environ. Cra tubing strings must be matched with compatible well jewelry. The first type is commonly referred to as hydrogen induced cracking hic and can occur where little or no applied or residual tensile stress exists. Is sulfide stress cracking an anodic or a cathodic process. Stress corrosion cracking of ferritic steel weld metal. Alloy b2 is damaged by intergranular stress corrosion cracking in the heat affected region when subjected to organic solvents comprising of sulfuric acid at 120oc. Nickel alloys are in general more resistant than stainless steels to several.
Stress corrosion cracking scc is a brittle mode failure that is well documented and has been extensively studied in all families of different engineering alloys. The following sandvik grades have very good or excellent resistance to chlorideinduced stress corrosion cracking. Tests were conducted using applied load with proof rings, basically following the. Below 20f 6c the diffusion rate of the hydrogen is figure 1. Notch tensile slow strain rate testing ntssrt method is used to evaluate the threshold stress intensity values kisscc.
Corrosionpedia what is sulfide stress cracking ssc. Ian sutton, in plant design and operations second edition, 2017. Ni lowers the low alloy steels resistance to both sulphide and hydrogen stress. Corrosion is a major concern in many industrial installations processing sulfides. In the hydroiodic acid at temperatures exceeding 177oc, alloy b2 was sensitive to transgranular stress corrosion cracking. It is a black solid that is produced by treating nickel ii salts with hydrogen sulfide. Heataffected zone liquation cracking in austenitic and. Field history the production unit is installed as close to the oil wells as possible and is used to separate gas and water from the crude oil. Jul 21, 2011 alloys with gross contamination would almost never make it through stressful operations such as rolling, drawing or stone setting without suffering severe cracking. Steels react with hydrogen sulfide, forming metal sulfides and atomic. Ssc resistance in terms of rah2sraair and time to failure was found to decrease with increase of material strength.
Ferritic steels are also resistant to cracking but may corrode. Industrial experience on the caustic cracking of stainless. Paul woollin, twi and manuel maligas, fmc corporation. In theory, any of the nickel chromium and iron nickel chromium alloys commonly used for high temperature service are subject to stress relaxation cracking. Solid solution nickel based alloys are hastelloy c, inconel 625 and incoloy 825. Sulfide stress cracking of nickelcontaining lowalloy. Sulfide stress cracking is the cracking of a metal under the combined action of tensile stress and corrosion in the presence of water and hydrogen sulfide a form of hydrogen stress cracking. Carbon and low alloy steels which are subjected to sour service environments may be susceptible to hydrogen induced cracking hic. However, there are many areas of similarities between the behaviors of the two alloy systems. Sulfide stress cracking ssc resistance of casing steels with different alloying chemistries i. Sulfide stress cracking nace mr01752002, mr0175iso 15156. The most common forms of wet h 2s cracking are hydrogen induced cracking hic, stressoriented hydrogen induced cracking sohic, and sulfide stress cracking ssc. The blistering damage tends to form parallel to the. Sulfide stress cracking an overview sciencedirect topics.
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